The gradient color used for the upper portion of the glossy effect when the control is in Normal state.
Below the button with its default value on the left and with the VistaColorGlossyEffectUpper property set to yellow on the right:
 
The gradient effect of this color can be enhanced/reduced through the VistaOpacityGlossyEffectUpper property
For further details about settings for the Vista's Aero style, see the How to manage colors of Vista's Aero style tutorial.
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